Chemical Name | Tris(Pentafluorophenyl)Borane |
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PubChem Substance ID | 87558752 |
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Reaxys-RN | 2931347 |
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Merck Number | 9755 |
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Synonym | Tris(perfluorophenyl)borane{LY} Tris(perfluorophenyl)borane{} {LY} Tris(perfluorophenyl)borane{} {} {LY} Tris(perfluorophenyl)borane{} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pe |
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Beilstein Registry Number | 2931347 |
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EC Number | 250-023-7 |
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Chemical Name Translation | 三(五氟苯基)硼烷 |
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LabNetwork Molecule ID | LN00145630 |
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InChI | InChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25 |
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MDL Number | MFCD00269813 |
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CAS Number | 1109-15-5 |
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Canonical SMILES | FC1=C(F)C(F)=C(F)C(F)=C1B(C2=C(F)C(F)=C(F)C(F)=C2F)C3=C(F)C(F)=C(F)C(F)=C3F |
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GHS Symbol WGK Germany | 3 |
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Precautionary statements | |
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- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
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Hazard statements | |
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- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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Hazard Codes | TXiXi,T,N,Xn,F |
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Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Gloves |
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Signal word | Warning |
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Storage condition | 2-8°C, protect from light, stored under nitrogen{LY} 2-8°C, protect from light, stored under nitrogen<0°C<;0Moisture Sensitive{} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {} {} |
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Safety Statements | |
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- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
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UN Number | UN 1268 3/PG 2UN2811 |
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Risk Statements | |
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- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Packing Group | III |
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Hazard Class | 6.1 |
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A useful component of Ziegler-Nattametallocene catalyst for polyolefins. {ALFA} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between -78o and ambient. Also effective for Michael additions of silyl enol ethers with enones: Synlett, 577 (1993). Low-temperature condensation of ester enol silanes with imines provides a route to ß-amino esters: Synlett, 963 (1994). Superior catalyst to TBAF for O-silylation with trialkyl or triaryl silanes. Alcohols and phenols are silylated using 2-8 mol% catalyst, with secondary and tertiary alcohols reacting faster than primary: J. Org. Chem., 64, 4887 (1999). Effective catalyst for reduction with Triethyl­silane, A10320, of alcohols and ethers to alkyls: Tetrahedron Lett., 40, 8919 (1999). Catalyst for highly efficient hydrosilylation of olefins with silanes R3SiH: J. Org. Chem., 67, 1936 (2002). {ALF} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between {ALFA} Catalyst for regioselective rearrangement of epoxides to carbonyl compounds: Synlett., 721 (1995), and efficient cleavage of epoxides with allyl and propargyl alcohols, amines and thiols: Tetrahedron Lett., 43, 3801 (2002). {SA} J. Am. Chem. Soc. 129 , 1880, (2007) 摘要 {SA} Merck 14 ,9755