Chemical Name | 3-Butyn-1-ol |
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CAS Number | 927-74-2 |
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Alfabeta Name | BUTYNOL 31--- |
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MDL Number | MFCD00002955 |
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PubChem Substance ID | 87563786 |
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EC Number | 213-161-9 |
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Beilstein Registry Number | 773710 |
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Reaxys-RN | 773710 |
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Synonym | 3-Butyn-1-ol{LY} 3-Butyn-1-ol{} {LY} 3-Butyn-1-ol{} {} {LY} 3-Butyn-1-ol{} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
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Chemical Name Translation | 3-丁炔-1-醇 |
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InChIKey | OTJZCIYGRUNXTP-UHFFFAOYSA-N |
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Wiswesser Line Notation | Q3UU1 |
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LabNetwork Molecule ID | LN00008189 |
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Canonical SMILES | C#CCCO |
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GHS Symbol TYPE OF TEST : LD50 - Lethal dose, 50 percent killROUTE OF EXPOSURE : IntravenousSPECIES OBSERVED : Rodent - mouseDOSE/DURATION : 100 mg/kgTOXIC EFFECTS : Details of toxic effects not reported other than lethal dose valueREFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05171
Warnings | IRRITANT, FLAMMABLE |
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WGK Germany | 3 |
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Hazard statements | |
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- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
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Hazard Codes | 3 |
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RTECS | ES0710000 |
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Precautionary statements | |
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- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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Signal word | Warning |
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Safety Statements | |
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- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
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Risk Statements | |
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- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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UN Number | 19861987 |
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Packing Group | III |
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Hazard Class | 3 |
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Storage condition | 2-8°C, stored under nitrogen{LY} 2-8°C, stored under nitrogenFlammables areaRT, stored under nitrogen{} {LY} 2-8°C, stored under nitrogen{} {} {LY} 2-8°C, stored under nitrogen{} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, st |
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{ALD} Beilstein:1(4)2219 {ALF} For examples of Sonogashira coupling with aryl iodides in the presence of trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491, CuI and Et3N in acetonitrile, see: J. Med. Chem., 38, 1837 (1995). {uni_hamburg} Short: II/14a {uni_hamburg} Short: II/2 {ALF} The triflate ester cyclizes on prolonged reaction with Na trifluoroacetate in TFA to give cyclobutanone: Org. Synth. Coll., 6, 324 (1988).